
Art. XLIII.—On the electro-motive order of certain Metals in Cyanide of Potassium, with reference to the use of this salt in Milling Gold.
[Read before the Wellington Philosophical Society, 29th January, 1876.]
While on an official visit at the Thames Goldfield I had many opportunities for observing the marked effect of Cyanide of Potassium, in preventing the flouring of mercury used in working off the blanketings. These blanketings I found have as a rule, a decidedly acid reaction, due in a greater part to the presence of ferric and ferrous salts soluble in water, and it is to the former of these salts, that what is commonly known as

“flouring,” is mainly due, in the process cited above; such ferric salts being able to either oxidize or chlorodize the surface of any mercury they may be in contact with, thus enfilming it with a compound, which being practically insoluble in water, or in water charged solely with the salts occuring in mineral workings, prevents that metallic contact taking place between detached mercurial globules, which is necessary to amalgamation.
In remedying or preventing flowing so occasioned, this salt, (Cyanide of Potassium) acts by decomposing these mercurial compounds and dissolving in part or wholly their constituent portions, while the surface of the mercury not thus floured, it keeps metallic, by preventing ferric salts acting in the manner stated; these salts being decomposed by this cyanide as they would by any other salt, having as it has, an alkaline reaction. *
In effecting these useful results it is thus seen that cyanide of potassium dissolves a portion of the mercury used; besides this there may be another portion of mercury, though a much smaller one dissolved away from the metal itself by the direct action of the cyanide upon it, aided by the free oxygen always present; this happens if no metal is dissolved in the mercury used, or is in contact with it, having a greater affinity for cyanogen than mercury has. Moreover, in thus contemplating the contingencies entailed or risked by the use of any alkaline cyanide in such milling operations, it must be remembered that both gold and silver are not absolutely insoluble in these cyanides.
Now, the loss of mercury in this way may not be serious, but if gold or even silver be thus lost (that is by its solution) even in much less quantity than mercury well could be, the loss then may be serious.
Now whether the loss of metal certain to be entailed by the use of cyanide of potassium, falls upon the mercury or upon the gold or silver of these blankettings, conjointly or separately, depends entirely upon this relative affinity of these metals for this salt, or in other words, it depends upon their electro-motive order therein.
According to our present knowledge in regard to this subject, mercury is positive both to gold and silver, under these circumstances, the loss of metal would therefore fall upon the mercury, which is of course desirable: thus we have it distinctly affirmed that “neither gold, silver, or platinum, directly percipitate mercury from its solutions,” But feeling the importance of this subject, and moreover having for various reasons grave doubts as to the correctness of these opinions, I investigated this matter for myself, and soon found that in reality mercury is not positive to either gold or
[Footnote] * I will reiterate here, the opinion of mine already published, that before putting in the cyanide to the blankettings, they should be made alkaline by the addition of common soda; leas cyanide would then be requisite, and thus working expenses be reduced.

silver in Cyanide of Potassium, as supposed, but very decidedly negative; thus metallic gold in contact with a solution of mercuric cyanides would rapidly dissolve and mercury be reduced.
A knowledge of this fact prompted me to determine the electro-motive order in Cyanide of Potassum, of the various metals which occur in our gold fields, or are employed in any way for milling gold. In the following list most of these will be found, it runs from negative downwards to positive:—
Electro-motive order of metals in Potassic Cyanide.
| Carbon. | Lead. |
| Platinum. | Gold. |
| Iron. | Silver. |
| Arsenic. | Tin. |
| Antimony. | Copper. |
| Mercury. | Zinc. |
Most, if not all the sulphides or other ores occurring in nature, are negative to the whole series. Any of these metals will generally precipitate the ores named below it from its cyanide solution. As already stated, gold and silver thus precipitate mercury, taking its place in the liquid, * which as is already known, silver precipitates gold. In relation to this, however, I find these two metals (gold and silver) are so nearly alike in their affinities for cyanogen, that this precipitation is a very slow process; cyanide of potassium even in contact with an alloy of silver and gold dissolves both, the silver however to the greater extent.
Thus it appears, a loss of gold by solution of it, must frequently happen whenever cyanide of potassium is employed to assist in the amalgamation of blankettings, or other auriferous stuff. In fact all that loss of metal occasioned by its solution, and most of which is, as we have seen a necessity involved in the working of the process itself, falls upon the gold and silver present, the mercury being positively protected from the action of this salt by these more valuable metals.
Further, as the rapidity of action of any exciting solution upon the positive element of a voltaic pair is (other things being equal) the greater the more electro negative to this solution the negative element is, it will happen that the solution and consequent loss of gold and silver in such operations will be the greater when they are carried on in berdans, as the
[Footnote] * The precipitation of mercury upon gold from a solution of mercuric cyanide is a very delicate and easy test for gold in stone, even when in the form of specks so minute as to be only visible by aid of a microscope; the yellow colour persistent at a red heat of the speck to be tested, and the instantaneous whitening of it occasioned by this cyanide may be taken conjointly as proving that it is gold.

iron of which their receiving part is made, as also the ball, is very negative to gold under the circumstances stated.
The loss of gold in this way will be also greater the more free cyanide of potassium there is present, proportional to the stuff; when the quantity is small the loss is perhaps not serious.
Whatever it is, however, I think it may be avoided, at least in a greater part by allowing the waste liquor from the blankettings to run in a thin stream over copper plates.
