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Volume 10, 1877
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10. Mineral Waters of the Rotorua District.

A very interesting series of waters has now to be described. They were obtained from the famous geysers and hot water springs of Rotorua by Captain Mair, at the suggestion of His Excellency the Marquis of Normanby, and are reported on in the “New Zealand Gazette” of the 3rd May last.

These waters are fifteen in number, and, as will be seen, while they are generally characterized by the highly siliceous nature of their saline matter, they divide as to their medicinal qualities into two classes.

In the following account of the results obtained, I copy the temperature of the several springs to which they refer, as also the physical description of these springs, from the notes of Major Mair, which were attached to the schedule forwarded with the water.

The quantitative results are stated in grains per gallon.

No. (1)—Is the water from Te Tarata, or the spring which forms the great white terrace of Rotomahana. This is a true geyser, having a large crater-shaped basin 90 feet in diameter, the lip of which is about 70 feet above the level of the lake.

This basin is emptied by an explosive effort, which throws the water to a height of 40 feet, emptying the basin, which again fills up rapidly. The water trickles over the ledges of the terrace, depositing fresh layers of siliceous sinter as it cools in its progress to the lake. The water in the basin has a deep azure blue colour, and a temperature of 210° Fah.

As received at the laboratory, it was faintly turbid, but without any deposit, colourless, and having an alkaline reaction.

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Analysis.
Silicate of soda 68.48
Mono-silicate of lime 1.62
" magnesia .53
" iron .51
Sulphate of potash
" soda 7.84
Chloride of potassium 2.87
"sodium 62.61
Phosphate of alumina traces
Lithia "
144.46

All but soda are mono-silicates, the little excess of silica, 7.66, is included in the soda-silicate.

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No. (2)—From Ta-pui Te Koutu, three-quarters of a mile from Ohinemutu, a large pool, 60 to 80 feet deep. The usual temperature of the water in this pool is from 90° to 100°, with westerly or southerly winds; but if the wind changes to N. or E., the water rises four feet in level, and the temperature increases to 180°, with a strong outflow. Thick masses of slimy Confervoid plants line the bottom of the pool. As received, the water was clear and colourless, with an alkaline reaction.

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Analysis.
Silicate of soda 32.12
Mono-silicate of lime 1.62
"magnesia .40
"iron .67
Sulphate of soda 7.06
Chloride of potassium .97
"sodium 29.94
Phosphate of alumina traces
72.78

Excess of silica over what is required to pass these bases as mono-silicates is 5.55.

No. (3)—From Turi-kore or Whakarewarewa, 2(¾) miles from Ohinemutu. The sample was taken from a waterfall which drains from a large pond 300 yards long, the reservoir of a number of boiling springs that are in continual activity. The temperature of this fall is from 96° to 120°. The water is of a dirty brown colour, and is in great repute among the Maoris for the cure of all cutaneous diseases. As received, it was clear and colourless, with a faintly acid reaction, which changes to alkaline on boiling the water.

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Analysis.
Silicate of soda 16.32
"lime 1.61
"magnesia 1.14
"iron .39
Sulphate of soda 13.47
Chloride of potassium 1.24
"sodium 53.61
Phosphate of alumina traces
87.78

No. (4)—From Kuirua, in the native village of Ohinemutu, on the shore of Rotorua Lake, where a strong stream flows from a number of hot springs which cover an extent of about 30 acres. This has a temperature of from 136° to 156°, and is so soft that clothes can be washed in it without the use

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of soap. It deposited a white flocculent sediment in the bottles, leaving the water clear, with a faint yellow tint, and an alkaline reaction.

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Analysis.
Mono-silicate of soda 2.57
"lime .34
"magnesia .12
"iron .31
Sulphate of soda 10.31
Chloride of potassium 2.08
"sodium 45.70
Phosphate of alumina traces
Silica, free 18.42
79.85

No. (5.)—From Koroteoteo, or the “Oil Bath,” at Whakarewarewa.— This is a strong boiling stream, the recorded temperature being 214° from two springs, one of which, surrounded by beautiful sulphur incrustations, throws a powerful jet to a height of 20 feet. The water is distinctly alkaline, or slightly caustic, which is probably the reason for it being termed an “oil bath.”

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Analysis.
Mono-silicate of soda 2.08
"lime 3.16
"magnesia .76
"iron .85
Sulphate of soda 7.49
Chloride of potassium 1.46
"sodium 66.34
"lithium traces
Silica, free 22.40
Phosphate of alumina traces
104.54

No. (6).—Otukapuarangi, the “pink terrace” of Rotomahana. This terrace has been built up round a great circular pool 180 feet in diameter, from which there is a strong outflow of clear bright water, having a temperature of 204° to 208°, and depositing siliceous sinter of a delicate pink tint in large quantities. As received, the water was faintly acid, changing to alkaline when boiled.

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Analysis.
Silicate of lime 1.91
"magnesia 1.16
Chloride of potassium 1.05
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Chloride of sodium 93.55
Sulphate of lime 10.96
"soda 1.01
Alumina as phosphate .54
Silica, free 43.95
Iron oxides traces
154.13

No. (7.) Manupirua, on the S.E. shore of Rotoiti, a beautifully clear pool 20 feet in diameter, having a temperature of 107° to 110°, at the foot of a high pumice cliff on the shore of the lake. The water is clear, with a bluish tinge, harsh to the touch, and deposits sulphur. This pool has a strong outflow of 40 to 50 gallons per minute, and is reported to have great curative properties.

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Analysis.
Mono-silicate of lime 1.51
"magnesia .77
"iron .99
Sulphate of soda 11.50
"lime 2.43
Chloride of potassium .47
"sodium 6.25
Silica, uncombined 8.53
32.45

No. (8.)—From Te Kauwhanga, 1(¼) miles from Ohinemutu, a powerful sulphur bath, having a temperature of 204°. The water as received was clear and colourless, with a distinct acid reaction, and evolving an offensive odour; it deposited a brownish sediment on being boiled. This bath is reputed to have great curative properties, and is known to tourists as the “Pain-killer.”

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Analysis.
Sulphate of potash 2.96
" soda 34.37
Chloride of sodium 59.16
"calcium 3.33
"magnesium 1.27
"iron .25
Phosphate of alumina traces
Silica 16.09
Hydrochloric acid 7.60
Sulphuretted hydrogen 2.01
127.04
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No. (9).—Cameron's Bath, situated in the same locality as No. 6. It is a muddy pool, 20 feet in diameter, having a temperature of 109° to 115°, but kept in a state of ebullition by a powerful escape of gas, which causes faintness when inhaled. The pool has no outflow, and the water is a dirty chocolate colour. As received, the water had a persistent acid reaction and offensive odour; it had deposited a siliceous sediment in large quantities.

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Analysis.
Sulphate of potash .94
"soda 33.47
"alumina traces
"lime 2.11
"magnesia 1.14
"iron 1.20
Phosphate of alumina traces
Sulphuric acid, free 76.79
Hydrochloric acid, free 7.28
Sulphuretted hydrogen .41
Silica 7.01
130.35

No. (10).—From Perekari, 1(½) miles from Ohinemutu. Temperature of water 130° to 150°. A boiling pool in a sand-spit near the lake, in which the water is discoloured, and has a very offensive smell. As received, it was clear and colourless, with a strong acid reaction; it had deposited a great deal of sediment, which consists of nearly pure silica.

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Analysis.
Sulphate of soda 26.75
"alumina traces
"lime 2.45
"magnesia 1.86
"iron .76
Chloride of potassium .63
Phosphate of alumina traces
Hydrochloric acid, free 5.38
Silica 18.17
56.00

No. (11).—From Te Kauwhanga mud bath, 1(¼) miles from Ohinemutu. A thick, brown, muddy water, covered with an oily slime, and having a temperature of 80° to 100°. When received, it had deposited a heavy muddy sediment, and had a persistent acid reaction, and an offensive odour.

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Analysis.
Sulphate of potash .77
" soda 23.71
" alumina 1.46
" lime 2.04
" magnesia 1.62
" iron 1.47
Phosphate of alumina traces
Sulphuric acid, free 7.60
Hydrochloric acid, free 7.66
Sulphuretted hydrogen 3.19
Silica 13.86
63.38

No. (12).—From Ariki-kapakapa, 2 miles from Ohinemutu, a small pool with a strong outflow, having a temperature of 160°. It deposits sulphur, and is surrounded by a great number of other baths and mud volcanoes. It is reported to have powerful curative properties. It was colourless as received, with a heavy deposit of silica, and an acid reaction, which was permanent at its boiling point.

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Analysis.
Sulphate of potash .38
" soda 12.51
" alumina .68
" lime 2.21
" magnesia 1.29
" iron 3.15
Phosphate of alumina traces
Sulphuric acid, free 13.96
Hydrochloric acid, free 2.62
Silica 18.15
54.94

No. (13).—Sulphur Bay Spring, on the edge of Lake Rotorua, formed by innumerable small jets forced up through sand, having a disagreeable odour, and a temperature from 90° to 100°. This bath is reported to have a powerful action on the skin, owing no doubt to the large quantity of sulphuric acid it contains. As received, it was colourless, with a slight flaky sediment.

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Analysis.
Sulphate of potash .07
" soda 8.37
" lime 2.50
" magnesia .93
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Sulphate of alumina traces
" iron 2.68
Phosphate of alumina traces
Sulphuric acid, free 18.02
Hydrochloric acid, free .86
Silica 10.08
Sulphuretted hydrogen 1.01
44.52

No. (14).—From Ti Kute, the “Great Spring,” 10(½) miles from Ohinemutu, a pool three-quarters of an acre in extent, having a temperature varying from 100° to 212° in various parts. It boils furiously, and dense volumes of steam are continually rising from it. The water is of a muddy brown colour, and contains a large proportion of sulphuretted hydrogen, and is reported to be wonderfully efficacious in cases of rheumatism and cutaneous disease.

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Analysis.
Sulphate of potash .59
" soda 12.66
" alumina 11.22
" lime 1.01
" magnesia .69
" iron 1.73
Phosphoric acid traces
Sulphuric acid, free .77
Hydrochloric acid, free 1.63
Sulphuretted hydrogen 5.74
Silica 12.40
48.44

No. (15).—From Te Mimi, Okakahi, a waterfall having a temperature of 90° to 112°. It drains from the preceding (No. 14), and only differs from it in being more dilute, and having a larger proportion of sulphuric acid, and less sulphuretted hydrogen.

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Analysis.
Sulphate of potash .13
" soda 4.78
" alumina traces
" lime 2.04
" magnesia .93
" iron .23
Phosphate of alumina traces
Sulphuric acid, free 12.48
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Hydrochloric acid, free 3.82
Sulphuretted hydrogen .98
Silica 4.12
29.51

I give below in a tabular form the respective quantities of the several substances found to be present in a gallon of each of these waters:—

No. Temperature. Silica. Iron Oxide. Alumina. Lime. Magnesia. Soda. Potash. Lithia. Sulphuric Acid. Chlorine. Sulphuretted Hydrogen. Total Contents.
Deg. Fah.
1 210-214 39.31 .30 .02 .77 .21 67.10 1.81 * 4.42 39.36 153.30
2 90-180 20.18 .30 .01 .77 .12 32.37 .61 3.98 18.63 76.97
3 96-120 13.63 .20 .01 .77 .45 39.84 .81 7.59 33.18 * 96.48
4 136-156 20.09 .10 .07 .16 .07 30.01 1.31 5.81 28.72 86.34
5 214 25.72 .46 * 1.24 .30 39.47 .91 * 4.22 40.96 113.28
6 204-208 45.66 * .54 5.54 .46 50.01 .66 6.33 57.27 166.47
7 107-110 10.31 .40 .06 1.41 .31 8.33 .30 7.91 4.01 * 33.04
8 204 16.09 .14 * 1.68 .62 46.36 1.60 * 20.72 46.72 2.01 135.94
9 109-115 7.01 .54 * .81 .38 14.61 .51 98.72 7.08 .41 130.07
10 130-150 18.17 .30 .04 1.01 .62 12.59 .39 18.16 6.21 57.49
11 80-100 13.86 .70 .38 .84 .54 10.35 .42 25.44 7.45 3.19 63.17
12 160 18.15 1.49 .20 .91 .43 5.46 .16 25.44 2.53 54.77
13 100-212 10.08 1.27 * 1.03 .31 3.94 .04 26.04 .84 1.01 44.56
14 90-100 12.40 .82 4.91 .83 .23 5.53 .32 19.49 1.59 5.74 51.86
15 90-112 4.12 .10 .05 .84 .31 2.09 .07 17.22 3.72 .98 29.50

Note.—The phosphoric acid present is omitted from this table, but appears in the detailed account of these waters.

None of them in their natural state gave any indication of the presence of either iodine or bromine, nor were any such indications observed for those waters which, for more rigorous testing, I evaporated to a small bulk. The waters I thus treated especially for these elements are Nos. 1–6 and 10–14, and as they represent all the kinds of waters of this series, I think it may be safely concluded that these substances are either absent, or, if present, are in quantities so small that they will not exercise any appreciable effect upon any one using these waters.

The metal lithium was found in waters Nos. 2, 7, and 9, but only in such small quantity as not to be readily detected, except spectroscopically.

As this is a substance having active medical properties, even when administered in small quantities, if continuously, it is often an important matter that its presence in any mineral water should be known to those who use it.

A perusal of these analytical results will show that the waters in question belong to two distinct classes—the alkaline and acidulous.

[Footnote] * Traces.

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The alkaline ones differ from those of this class which have been already described in being silicated instead of carbonated. They are, in fact, eminently siliceous waters comparing with the hot spring water of Iceland; any carbonic acid which may have been present in the water when situated at a great depth, being eliminated therefrom as it reached the surface, in consequence of the superior affinity of silicic acid for alkaline bases at elevated temperature and low pressure.

This substitution of silicic for carbonic acid will only affect the waters for therapeutic purposes where they depend in part or wholly for their desired effect upon the presence of carbonic acid. When the alkaline character of the water, however, is alone to be regarded, I do not see why these silicated waters of ours should not (when of about the same strength) be quite as useful as those alkaline waters of the European spas in which the alkalies are combined with carbonic acid, and when neither iodine nor lithium are present to any notable extent. The waters of this kind are Nos. 1–6.

The waters of the other class—the acidulous—are also remarkable as being those from which carbonic acid has been wholly eliminated; but in this case a so-called mineral acid, hydrochloric or sulphuric acid, is the substituting one in place of silicic acid as in the waters of the former class. Silicic acid is, however, generally present, but in a free state as a hydrate, all the silica which is entered in the analytical results of these waters being of the kind known as soluble silica. The waters of this class are Nos. 8–15. Certain of these are hepatic, some strongly so, that is, they contain sulphuretted hydrogen in quantity, and it is only the waters of this kind which it would be safe as yet to look upon as having useful medicinal qualities to a remarkable degree.

These waters are Nos. 8, 9, 11, and 13–15, or those of Kauwhanga, Cameron's Bath, Te Kauwhanga, Sulphur Bay Spring, Ti kute, and Te mimi, Okakahi, respectively.

These waters should prove efficacious in cases of rheumatism and skin diseases. The more palatable ones will of course be those which are the least acidic.

I cannot find that these waters strictly compare with any of those afforded by the European spas; the free hydrochloric or sulphuric acid present in them clearly separating them therefrom.