Go to National Library of New Zealand Te Puna Mātauranga o Aotearoa
Volume 10, 1877
This text is also available in PDF
(245 KB) Opens in new window
– 456 –

Art. LXX.—Notes on a Deposit in the Shaft of the Pumping Association.

[Read before the Auckland Institute, 20th August, 1877.]

I Exhibit samples of the lime deposit which lately formed in the pumps and upon the timbers of the United Pumping Association shaft; the slab was broken off one of the timber frames in the shaft at a depth of 540 feet from the surface. I will briefly give a few details of its mode of occurrence.

This incrustation was first observed when the shaft was about 530 feet deep; in sinking at that depth a large body of quartz had been cut through, and when the strata upon which the quartz was lying was cut into, a great change took place; the water formerly was acidulous, it now became alkaline, and it was highly charged with carbonate of lime, which it held in solution and precipitated as it came in contact with the carbonic acid gas in the shaft. This deposit formed remarkably fast, and did not continue regular, some weeks it would form more in thickness than it did in others. The average thickness it formed on the buckets of the pumps was about a quarter of an inch in a week; it would coat a pick handle or drill in twelve hours, and this was a great source of annoyance to the men working in the bottom of the shaft, as the pick and hammer handles got coated with

– 457 –

the deposit and cut their hands, the skin being worn through, as they were actually working with tools encased in stone. At this time it also formed in the lines of the skin on the men's hands and arms, and took a great deal of cleaning and rubbing to get rid of.

It speedily began to act upon the working of the pumps, and castings had to be got specially constructed to disconnect the pump bucket from the rods below, as it would not come up the column, and as time went on the column had to be chipped the whole length inside to keep the water space clear; this was done by slinging five or six men at a time on to a rope and lowering them down into the column, which they chipped with chiselpointed hammers. This operation would take about three days, but it wa not all performed at the same time, one part of the column would be done when we had to change a bucket, and another part was done at next changing of bucket, and so on, and by this means the lift was kept clear.

The twenty-five inch lift was cleared its entire length by this means three different times, and the working barrel at the ends of the stroke had to be chipped fortnightly.

The deposit was very irregular while forming, with regard to hardness. Sometimes it would form hard, sometimes soft; when it did form soft there was always more of it; sometimes it would form three-eighths of an inch in a week; when so, for two or three hours after the bucket came to the surface the incrustation was quite soft, but it hardened very soon on exposure to the atmosphere.

There is a peculiarity in the deposit, viz.,—it always forms in layers, and these layers change colour without any apparent cause—one layer may be white, the next one red, and it would keep changing in shade from pure white to a dark brown.

Where the water was hottest the deposit was most, and in some parts of the workings, on the thermometer being held in the stream as it issues from the rock, it will rise to 108° Fahr.; 100° is quite usual.

Since the crosscuts have been driven on both sides of the shaft the deposit has ceased forming in the pumps, and it now forms on the sides of the drives. The drives north and south for a distance of 300 feet on both sides of the shaft being now all coated with it, it also forms in the shoots in which the water is conveyed after it leaves the pumps on the surface. This deposit is not like what is formed below, being quite soft and having more of an earthy appearance.

There is an old shoot on the surface not now in use, along which a small quantity of water has been running; this shoot is about eight inches square inside and it has completely filled up with deposit during the last two months.

– 458 –

As may be readily imagined it was a great source of trouble and expense to keep the pumps at work while the incrustation was forming inside them, and now that it has ceased forming there, I hope we shall never have a repetition of it. I have sent this slab thinking it may find a place in the Museum.

Note.—Specimens of this incrustation were sent to the Colonial Laboratory in 1875, and reported on as follows:—

“No. 1753 is an incrustation taken from the cylinder of that large pump used at the Thames diggings for draining the lower levels of certain claims there adjoining the beach. It appeared to have incrusted a portion of this cylinder evenly over to a thickness of about one-quarter of an inch, and is very hard, also impervious to water, and presents to the naked eye an amorphous appearance, except on its inner side, this being, on the other hand, manifestly semi-crystalline; and besides is interspersed, though somewhat rarely, with crystals of iron pyrites. The pyrites is in all probability however, merely a mechanical deposit.

“The annexed results of an analysis made of a portion of this incrustation show it to be essentially carbonate of lime. As it has certainly been deposited in this form from some solution of it, and as the solvent for it in this case has most probably been water charged under a considerable pressure with carbonic acid it would appear that this incrustation has been induced by the escape of carbonic acid, caused by reducing the pressure and therefore the capacity of the water for carbonic acid by the action of the pump, resulting of course in a lowering of its solvent power for carbonate of lime:—

[The section below cannot be correctly rendered as it contains complex formatting. See the image of the page for a more accurate rendering.]

Analysis.
“Carbonate of lime 85.94
Carbonate of magnesia .84
Iron oxides, with alumina 6.69
Siliceous matters, insoluble in weak acid 2.18
Soluble silica .44
Water 2.17
Alkalies, sulphur, etc. 1.74
100.00′ Ed.