
[Read before the Wellington Philosophical Society, 5th October, 1910.]
Contents.
Introduction.
Outline of geology.
Previous petrographic descriptions.
Special petrography—
| (1.) |
Rocks of the auriferous series. Period.”
|
||||||||||||
| (2.) |
Stratified tuff of the Grand Junction shaft. |
||||||||||||
| (3.) |
Andesites and tuffs of the “Second
|
||||||||||||
| (4.) |
Rhyolites.
|
||||||||||||
| (5.) |
Andesitic rocks of doubtful age. |
Literature.
Introduction.
In leisure time during the years 1903–5 the writer was engaged in making a petrographical study of the rocks occurring in or near the Waihi Goldfield. The main object of this study was to obtain data that would be of value in a detailed investigation of the geology and the mineral veins of that district. It was thought that such an investigation would assist in defining the limits of the auriferous rocks, and in discovering the mode of origin of the veins and the source of their metalliferous constituents. More especially it was hoped that clues to the laws regulating the distribution of values in the auriferous veins and the depth to which payable ore might be expected to persist would be found.
In this work the writer was interrupted by a change of residence and occupation. So far as his researches went, the possibility of data of high economic value being obtained by close petrographical study, by chemical analysis, and by other methods of scientific investigation was clearly indicated. Since the study as originally planned by the writer remains woefully incomplete, it is not possible to set forth all that might be accomplished by scientific work, nor is it advisable to state various conclusions that are not fairly well supported by the evidence actually obtained.
The object of the present paper is to put on record the main results of the writer's petrographical work, with such descriptions as may be useful to future workers. It is desired especially to direct attention to the nature of the rocks enclosing the veins of the Waihi Mine, and to the type of alteration that these rocks have undergone.
Outline of Geology.
The oldest rocks exposed in the neighbourhood of Waihi are the altered lavas in which the gold-bearing lodes of the Waihi, Grand Junction, and other mines occur. These rocks are very generally considered to be quartz-bearing andesites and dacites, although a few years ago, when various samples from the Waihi mines were determined by Professor W. J. Sollas as altered pyroxene-rhyolites, some doubt as to their true nature arose.

The term “auriferous series” may be applied to the rocks in question as a non-committal name with respect to their petrographical character. There is as yet no very positive evidence available concerning the age of the auriferous series, but it may be assumed as Eocene, or possibly early Miocene.
After the rocks of the auriferous series had been subjected to more or less denudation, and very probably to the internal change known as propylization, a limited amount of material accumulated in valleys or other hollows that were doubtless occupied by lakes. Such material, in the form of well-stratified tuff, is exposed in the Grand Junction A or No. 1 shaft at a depth of 620–640 ft. below the surface, and about 240 ft. below present sea-level.
Soon volcanic activity on a large scale was resumed, and a second great outpouring of andesitic lavas took place. These rocks form high hills to the north of Waihi, and appear on the surface in the open valley west of Martha Hill. They also occur to an unknown extent under the younger rhyolitic rocks at and near Waihi. In point of age these younger andesites and their accompanying tuffs (developed only very slightly near Waihi) may be referred to the Beeson's Island group of McKay, or to Fraser's “Tertiary Volcanic Rocks of the Second Period.” To the Beeson's Island group may also be assigned the great development of tuffs, in places much intersected by dykes, seen along the coast east and north-east of Waihi.
After the eruption of the “Second Period” volcanics a comparatively brief period of rest from igneous activities was followed by the outpouring of acid lavas. Some of these were rhyolites of the peculiar brecciatedlooking type known as “wilsonite” (11,* vol. 1, pp. 123, 124; vol. 2, pp. 46, 138). This rock forms the greater part of the so-called “Waihi Plains,” and wraps partly round the outcrops of the auriferous series. With it are associated small amounts of tuff.
Between Waihi and the coast there appear spherulitic rhyolites, probably of approximately the same age as the wilsonite, but possibly older. These are well developed east and north-east of Waihi. They are seen on the coast north of Houmunga Bay, at Waihi Beach (where they contain auriferous veins), and at Mount Hikuragi, a conspicuous elevation a few miles south of Waihi.
Breaking through the wilsonite in various places, and therefore of younger age, are light-coloured rhyolites of harsh texture. These are observable mainly in and near the Town of Waihi, and are also well seen near Waikino, four miles to the west.
The various rhyolites may be provisionally regarded as of Pliocene age, and as contemporaneous with the great rhyolitic flows of the central part of the North Island.
Some hornblende-andesites that occur near Waihi are younger than any of the other andesites, but their age with reference to the rhyolites is uncertain.
The recent surface accumulations of the Waihi district, consisting of a little conglomerate, talus, clay, &c., are of litte moment from a purely geologic point of view. The loamy clay on the slopes of the Martha Hill is apparently largely of aerial origin, and might therefore be called loess. Since this material furnishes a cheap and efficient “filling” for the Waihi Mine workings it has considerable economic value.
[Footnote] * This and other numbers similarly inserted in brackets refer to list of literature at end.

Previous Petrographic Descriptions.
In 1870 Sir James Hector (1) passed through the Waihi district. Apparently he considered the andesitic rocks of the neighbourhood to be of doleritic and basaltic character. On the Waihi Plains he noted the presence of “trachyte” [? wilsonite]. To the eastward Hector observed hills capped by “true rhyolite” or “quartzose trachyte” [spherulitic rhyolite with quartz phenocrysts], and on the coast-line cliffs of “true trachyte agglomerate.”
In 1882 Mr. S. H. Cox (2), now Professor of Mining in the Royal College of Science and Technology, London made a flying survey of the Ohinemuri Goldfield. Cox mapped the rocks near Waihi as “tufaceous sandstone” [propylitic facies of andesites and dacites], dioritic rock, anamesite (?), and rhyolite.
About 1883 the late Professor G. H. F. Ulrich determined by microscopic study the andesitic nature of the gold-bearing rocks of the Thames district. Ulrich's work, though known only through a communication made to Professor F. W. Hutton (3, p. 19) may be regarded as the most important contribution ever made to New Zealand petrography. Henceforward the auriferous rocks at Waihi and in other parts of the Hauraki Goldfield if resembling those at Thames were regarded as altered or decomposed andesites—an essentially correct conclusion.
In 1897 Professor James Park, apparently on the strength of microscopic examinations specially made by Ulrich (3, pp. 27, 28) referred to the rocks of the Waihi auriferous series as propylite resulting from the alteration of hypersthene-augite-andesite (3, pp. 26, 87).
It ought to be remarked that the two rock-specimens determined by Ulrich were probably both from the andesitic rocks overlying the auriferous series, and hence Park's determination of the latter as altered hypersthene-augite-andesite can hardly be regarded as authoritative. Apparently this writer at that time regarded the Waihi andesites as all of one type and of one geological age.
Park described the other volcanic rocks at Waihi as rhyolites, of which he mentioned there were at least two distinct flows.
In the same year as the publication last cited an important report on the geology of the Cape Colville Peninsula appeared from the pen of Mr. Alexander McKay (4). On page 59 are a few sentences referring to the auriferous rocks in the neighbourhood of Waihi. These are placed in the “Kapanga group,” but, evidently by design, no specific rock-names are given. In the absence of proper microscopic determinations McKay's attitude of reserve may be regarded as being highly correct. The various rhyolites near Waihi are described (pp. 67, 68) as “spherulitic rhyolite,” “a remarkable brecciated rhyolite” (wilsonite), and “an earthy compact rhyolite.”
Largely as a result of the boom in gold-mining that prevailed during the years 1895–97, a number of papers in which the nature of the rocks at Waihi was more or less cursorily mentioned made their appearance, but for the purpose of the present article it is not necessary further to mention these publications, which were nearly all of an ephemeral character.
In 1899 the late Mr. F. Rutley, in association with Professor Park (5), described several rhyolites from the neighbourhood of Waihi, as well as a doubtful silicified rock, a supposed silicified andesite tuff, and a supposed silicified andesite. Rutley was the first to observe tridymite in the rhyolites

of Waihi and other parts of the Hauraki goldfields. His work on the silicified rocks plainly pointed the way to a theory of metasomatic replacement of country * by vein-material.
The next year Park (6) described a hypersthene-andesite stated to be from the 300 ft. level (probably No. 3 or 279 ft. level) of the Waihi Mine. He noted as original minerals plagioclase, some (probable) orthoclase, hypersthene (much decomposed), a little enstatite, a little possible augite, some magnetite, and perhaps quartz. The possible presence of original hornblende (indicated by lozenge-shaped spaces crowded with dark dust) was also observed. Secondary minerals were magnetite, haematite, serpentinous matter, calcite, and quartz.
Park's determination of orthoclase in this, perhaps the first specimen of rock from the Waihi Mine ever microscopically examined, is noteworthy, but, as will be shown on later pages, the primary origin of much or perhaps of all the orthoclase in Waihi andesites and dacites may be strongly questioned.
In 1902 the writer, without having made any microscopic examinations, but relying on the statements of previous observers and on the results of analyses made by himself and others, stated that “the Waihi reefs lie in a decomposed andesite or propylite, which there is some reason to believe is older than the bush-clad andesite of the hills to the north and west.” This latter is “of a different character to that forming the [Martha] hill itself” (7, p. 165).
Two years later, the writer, having examined a number of sections of Waihi rocks, incidentally mentions that the “country” in which the lodes occur is “decomposed quartz-andesite” (8, p. 429).
In 1905 Mr. Waldemar Lindgren, the well-known economic geologist, made a visit to Waihi. In a subsequent article on the Hauraki goldfields (9) Lindgren states, “Mr. Park determines it [the country of the Waihi Mine] on authority of Mr. Hutton [? Professor Ulrich] as hypersthene-andesite; all of it, however, is not of that character, for specimens collected on the 500 ft. level † in the footwall of the Martha lode consist of a dark-green porphyritic rock with recognisable. Phenocrysts of corroded quartz and orthoclase. The ferro-magnesian silicates, probably pyroxene, are altered to serpentinoid aggregates. Lime-soda feldspars could not be definitely recognized, while the groundmass is micropoikilitic, and certainly contains much quartz. The rock is thus either a dacite or is intermediate between a dacite and a quartz-bearing trachyte.”
Lindgren also says, “The rock adjoining the sulphide ore [at the 500 ft. level, Martha lode] has suffered great alteration, although seemingly fresh. Pyrite and a carbonate, probably calcite, are abundant in metasomatic development, as is a brownish-green serpentine. The veinlets traversing it contain much secondary orthoclase or valencianite, together with quartz and calcite.”
A letter written by the writer commenting on Lindgren's article remarks that the lode-bearing rock at Waihi “might perhaps be more correctly called quartz-andesite or dacite” (10, p. 861).
In 1905 and 1906 appeared “The Rocks of Cape Colvile Peninsula, Auckland, New Zealand” (11). In this important work, consisting of
[Footnote] * The term “country rock,” now so commonly employed by writers on economic geology, is, strictly speaking, tautological. The miners of the Hauraki Goldfield, as a rule, employ the more correct expression, “country.”
[Footnote] † Probably the No. 6 or 555 ft. level.

petrographical descriptions by Professor W. J. Sollas, with additional matter and micro-photographs by Mr. Alexander McKay, nine rocks from Waihi mines are described. Of these, one is classed as a doubtful andesite, two as pyroxene-rhyolites or andesites, five as rhyolites (mostly pyroxenerhyolites), and one is called “a much-decomposed altered quartz-feldsparpyroxene rock.” This last rock may possibly belong to the andesites overlying the auriferous series.
Sollas also describes various andesites and rhyolites from the neighbourhood of waihi. reference will be made to some of his descriptions on a later page.
In 1908 Dr. J. M. Bell and Mr. Colin Fraser, in an article on the Waihi Mine (12), refer to the mine-rocks as altered dacites, containing stringers of calcite, quartz (both chalcedonic and highly crystalline), orthoclase (variety valencianite) in minor amount, and pyrite. They remark, “The vein-bearing rocks have been described as rhyolites, but careful chemical and petrographical investigation have led the writers of the present paper to classify them as dacites” (12, p. 388).
In the same paper reference is made to the younger andesitic and dacitic lavas and tuffs that overlie the vein-bearing dacites. Three types of rhyolite—namely, (a) spherulitic rhyolite, (b) pumiceous brecciated flow rhyolite (“wilsonite”), and (c) grey lithoidal rhyolite—are recognized.
Dr. J. Malcolm Maclaren, who is well acquainted with the Hauraki goldfields, has also questioned Sollas's determination of the country in the Waihi Mine as a “hornblende-pyroxene-rhyolite.” After quoting Sollas's description (11, vol. 2, pp. 67, 68), Maclaren remarks, “In view of the occurrence of orthoclase (valencianite) in the lodes of Waihi, and of the exceedingly altered state of the country, it is conceivable that the orthoclase found in the above rock may be valencianite due to secondary action; indeed, considerable indication of such a growth is outlined in the foregoing petrological description [Sollas's]. It is therefore probable that the highly decomposed rocks of the Waihi area do not represent original rhyolites, but a local succession of andesites, dacites, and even more acid rocks that have been so thoroughly altered by solfataric solutions that many of their original characters have disappeared” (13, p. 315).
In 1909 Mr. A. M. Finlayson, in an article entitled “Problems in the Geology of the Hauraki Goldfields, New Zealand” (14), remarks on the occurrence of valencianite (adularia) as a secondary product in the completely altered rocks of Waihi. He isolated and analyzed the mineral, with the following results :—
[The section below cannot be correctly rendered as it contains complex formatting. See the image of the page for a more accurate rendering.]
| SiO2 | 65·85 |
| Al2O3 | 18·48 |
| K2O | 11·25 |
| Na2O | 4·11 |
| 99·69 | |
| Specific gravity | 2·61 |
Finlayson says, “In view of the fact that this orthoclase is, in the specimens examined, of secondary origin, while the primary feldspars are soda-lime varieties, the original rocks appear to have been in the main andesites and dacites. …. The presence of soda in the Waihi

valencianite is doubtless due to its derivation from soda-feldspars by the action of the potash-bearing vein-solutions" (14, pp. 634–35).
Finlayson also made a series of instructive analyses of specimens, all except one of which were from a crosscut to the Empire vein at the 850 ft. level of the Waihi Mine. These analyses show clearly the transition from “chloritized hornblende-dacite,” with 58·39 percent. of silica, to “altered dacite,” with 61·78, 69·35, and 76·61 percent. of silica, and finally to “replacement ore,” with 85·65 percent. of silica.
In his latest work Professor Park refers to the rocks of the Waihi Goldfield in much the same terms as in 1897. The auriferous rocks are called “altered andesites and dacites” (15, p. 349).
In a recent paper, entitled “The Waihi Goldfield” (16), Dr. J. M. Bell mentions the Waihi rocks by the same names as in the previous article by himself and Mr. C. Fraser (12).
Special Petrography.
From February, 1903, to May, 1905, the writer made and microscopically examined a large number of sections from specimens of rocks occurring in or near the Waihi district. These will be described and discussed under the following headings :—
| (1.) |
Rocks of the auriferous series. |
| (2.) |
Stratified tuff of the Grand Junction shaft. |
| (3.) |
Andesites and tuffs of the “Second Period.” |
| (4.) |
Rhyolites. |
| (5.) |
Andesitic rocks of doubtful age. |
(1.) Rocks of the Auriferous Series.
(a.) Quartz-andesites and Dacites.
The specimens from which sections were made are for the most part from Nos. 5 and 6 levels * of the Waihi Mine. These levels correspond to depths below the surface of 445 ft. and 555 ft. respectively as measured from the collar of No. 1 shaft. Three or four are from higher levels of the Waihi Mine, and a few come from the Grand Junction and Waihi Extended Mines at depths of approximately 480 ft. to 500 ft. below the surface.
Macroscopically the specimens are generally dark-grey or greenish closegrained rocks, showing porphyritic feldspars of moderate size and a few phenocrysts of glassy quartz. Numerous dark altered crystals are referable to pyroxenic or amphibolic minerals. A marked effervescence with cold dilute hydrochloric acid in practically all specimens indicates the presence of calcite.
Under the microscope most sections exhibit many crystals of moderately or well twinned plagioclase which by the extinction angles and relative indices of refraction as compared with other minerals and with Canada balsam are shown to be mostly acid labradorite. Andesine is present in many cases. The twinning is nearly always on the albite law: pericline twinning is somewhat rarely seen. Zonary banding, pointing to a difference in the composition of individual crystals, is quite common. Nearly universally, if not always so, the more acid feldspar (usually near andesine) is on the outside.
[Footnote] * These are the numbers given in published plans and reports; at the mine itself the practice is, or was, to call these levels Nos. 6 and 7.

As regards alteration, the plagioclases vary from quite fresh individuals showing good twinning to highly decomposed crystals in which the original twinning has all but disappeared, and is indicated only by a faint banding in portions of the crystals. * From these it would seem but a small step to the highly altered feldspars without a trace of twinning that are commonly present. The alteration-products are largely calcite and quartz. Some muscovite is occasionally present in small flakes, and in odd instances haematite fills the cleavage-cracks. The most-altered plagioclases (those with just a trace of repeated twinning) show a mosaic which is mainly secondary quartz and feldspar. The exact nature of the latter is not always apparent, but in some cases it can be determined as valencianite. In one instance where a microscopic vein of quartz and calcite crosses a section valencianite may be observed replacing a crystal of plagioclase intersected by the vein.
Nearly all the sections have feldspar crystals that by their optical properties appear to be orthoclase. These are in some instances fresh, and show Carlsbad twinning. One such crystal, with extinction angles of 19 ¼° and 19 ¾°, has one half slightly but decidedly zonary. Many of the orthoclases, however, are much altered, and consist mainly of a mosaic of quartz and calcite, with some muscovite, iron-oxide, &c. The apparently residual feldspar in many cases suggests valencianite, but to prove decisively that it is really secondary is no easy matter. A consideration, however, of the manner in which transition forms occur between undobted plagioclase and the crystals in question leads to the conclusion that the latter must represent highly altered lime-soda feldspars. In this connection the almost invariable presence of calcite is strongly suggestive of an original lime-content.
Original quartz grains are present in all the sections. Some sections have only one or two small quartz grains, others have several comparatively large phenocrysts. All the quartz grains have rounded outlines, in many instances with deep bays, and thus show clearly the effects of corrosion by a fluid magma. Very rarely can an approach to bi-pyramidal outlines be seen. Occasionally the grains of quartz seem to include small rounded patches of the groundmass, but these are probably all, or nearly all, embayments cut across in the sectioning.
Ferro-magnesian minerals are represented by fairly numerous phenocrysts, generally entirely altered to chlorite, serpentinous matter, ironoxides, &c. In a few sections augite is quite recognisable. Hypersthene or similar rhombic pyroxene seems to have been originally present in every section. Hornblende is probably represented in odd sections by dark lozenge-shaped masses similar to those described by Park (6, p. 343).
The other original minerals present call for little description. Small crystals or grains of magnetite are always seen. Some of these, however, are presumably due to the decomposition of ferro-magnesian minerals. The magnetite is often partly altered to a leucoxenic-looking mineral, but this, according to Finlayson, is probably siderite. Apatite can usually be distinguished as small needles in the feldspars. Zircon is possibly present in one or two sections.
The groundmass in the various sections varies considerably in amount, but may be said to form much more than half the rock, as a rule. In the
[Footnote] * Sollas speaks of similar feldspars as showing traces of microperthitic structure (11, vol. 2, pp. 18, 54).

fresher examples an abundance of small feldspar laths crowded together in more or less parallel arrangement is present, and thus the structure is decidedly inclined to be pilotaxitic; but, since calcite and other alteration-products are invariably present to some extent, the original pilotaxitic (or possibly hyalopilitic) structure is partly obscured. More commonly the groundmass consists mainly of a granular mosaic of quartz, feldspar, and calcite, with minor amounts of other minerals.
(b.) Wall-rocks.
The rocks now to be discussed are from the same localities as those coming under (a), except that, as indicated by the heading, the specimens examined were obtained either within a few feet of the larger veins or were taken from the actual walls of the veins.
Macroscopically the wall-rocks are evidently more highly altered than those some distance from the veins. They are lighter-coloured, and do not effervesce so freely with hydrochloric acid. Feldspar and, less commonly, quartz phenocrysts may be observed. Ferro-magnesian minerals, while usually distinguishable, are always intensely affected by decomposition.
Under the microscope the sections show extreme alteration. The feldspar phenocrysts are nearly all so decomposed that the identification of their original character becomes uncertain. In one or two sections fairly fresh binary twins of orthoclase may be recognized. In most of the sections there are feldspars showing traces of repeated albite twinning, and hence it may be concluded that these feldspars were originally plagioclase. In the main, however, albite twinning is absent, and, since the refractive index of any recognizable feldspar is well below that of Canada balsam, the mineral approaches orthoclase or anorthoclase in its characters. The most highly altered feldspars consist of a mosaic of quartz and feldspar, with minor quantities of calcite and “kaolinitic” matter. In some cases the feldspar of the mosaic is evidently secondary, and therefore to be termed “valencianite.” In other instances, however, its secondary nature is less certain, though appearances are generally quite consistent with such a conclusion. The so-called “kaolinitic” matter mentioned above is strongly suspected to be near sericite in composition, but in the absence of chemical tests its exact nature seems indeterminable.
Original quartz grains appear exactly as in the rocks coming under the last heading, except that they are in some instances in optical continuity with clearly secondary quartz, a phenomenon not observed in the less-altered country.
The ferro-magnesian minerals are entirely altered to chloritic material, with a little iron oxide, &c., so that the original species can hardly be more than guessed at. Rhombic pyroxene may perhaps be assumed as having been present. Primary hornblende is doubtfully indicated by the presence of many small magnetite grains in some of the chloritic matter which has outlines possibly refereable to amphibole.
Other original minerals include a little magnetite, often with leucoxene like alteration (? to siderite), and a few small needles of apatite. A section made from a diamond-drill core obtained in the Grand Junction Mine at a depth of nearly 800 ft. from the surface shows a nest of some mineral with the appearance of tridymite.
The groundmass in the sections of wall-rocks is a granular mosaic composed largely of quartz, with probably more or less valencianite, a little

calcite, &c. An almost opaque streaky substance, nearly white by reflected light forms much of the groundmass. Such material is often referred to as “kaolinitic,” but, as previously remarked, is probably near sericite in composition.
Of secondary minerals not already mentioned, pyrite, almost invariably in small cubes, is the most conspicuous. Epidote or allied mineral may very rarely be present.
(c.) Vein-material.
The vein-material of the Waihi mines largely replaces country, and therefore will be discussed to some extent. In the upper levels of the Waihi Mine the vein-material is quartz, with a little clay, iron and manganese oxides, &c. Some of the quartz is crystalline to the eye, and has obviously been deposited in open spaces. Much, however, is of flinty or chalcedonic appearance. Sections of this chalcedonic material show that it is mainly an indefinite kind of mosaic that resembles the quartz mosaic seen in highly altered wall-rock, and it therefore suggests replacement or silicification of country. This view is supported by a study of the ore from lower levels. The following analysis * of a representative piece of “oxidized” ore from one of the upper levels shows that the material is far from being pure quartz :—
[The section below cannot be correctly rendered as it contains complex formatting. See the image of the page for a more accurate rendering.]
| SiO2 | 89·98 |
| Al2O3 | 1·82 |
| Fe2O3 (including FeO calculated to Fe2O3) | 5·62 |
| MnO and NiO | 0·39 |
| H2O at 100° C | 0·26 |
| Loss on ignition | 1·60 |
| 99·67 |
Gold, 2 oz. 5 dwt. 17 gr. perton. silver, 10 oz. 2 dwt. 12 gr. perton.
Sections made from a portion of the specimen that furnished the material for the above analysis show ore with replacement characters seamed by tiny veins of crystalline quartz.
In Nos. 5 and 6 levels (445 ft. and 555 ft.) of the Waihi Mine the presence of partly unsilicified country in the veins is easily recognized. In places quite a large proportion of the vein-material is dark-coloured rock, which in some instances is actually less altered than the wall-rock.
Sections of the less-silicified rock from the veins are very like those of the wall-rocks. Feldspar is the chief original mineral recognizable. Some individuals with feldspathic outlines are mosaics of quartz and presumably secondary orthoclase or anoorthoclase, together with more or less kaolinitic, or more probably sericitic, material. In places fresh, easily recognized valencianite with good cleavage and low index of refraction occurs. Binary twins of apparent orthoclas are observable in at least one section. In several slides traces of repeated albite twinning are quite distinguishable in the feldspars, and in one section acid labradorite, and perhaps andesine, can be identified. Some original quartz in rounded grains is present in all the slides. Ferro-magnesian minerals are in general even more altered than in the wall-rocks, and are represented by somewhat indefinite masses of chlorite and other minerals, particularly pyrite, so that the original species
[Footnote] * See 7, p. 182.

cannot be ascertained. The groundmass is more or less a quartz mosaic. Other minerals present in it are magnetite, pyrite, and calcite.
(d.) Discussion of Nomenclature.
[The section below cannot be correctly rendered as it contains complex formatting. See the image of the page for a more accurate rendering.]
With the notable exceptions of Sollas, and to some extent of Lindgren, the various writers who have been quoted on previous pages substantially agree in describing the rocks of the auriferous series as andesites, quartzandesites, or dacites. Lindgren hesitates between dacite and quartztrachyte as a name for these rocks; but this geologist examined wall-rock from the Waihi Mine only. It would also seem to be the case that all, or nearly all, Sollas's determinations were made from samples of highly altered rock adjoining large veins. Had Sollas been given an opportunity of examining a series of less-altered specimens taken some distance from the larger ore-bodies it is probable that he would have reached conclusions more in agreement with those of New Zealand workers. * As matters stand, however, the presence of much apparent orthoclase has given rise to a difficulty in naming the auriferous rocks.
From the petrographical descriptions given on the preceding pages it will be gathered that there is much evidence for the view that most, if not all, of the supposed original orthoclase is of a secondary character, replacing original lime-soda feldspar, as has already been suggested by Maclaren and Finlayson. Thus the determination of the auriferous rocks as quartz-andesites or dacites (these terms being here used as all but identical in meaning) may be regarded as proved, at least as regards the Nos. 3, 4, 5, and 6 levels (279 ft., 353 ft., 445 ft., and 555 ft.) of the Waihi Mine, the 500 ft. level of the Waihi Extended Mine, and the 494 ft. level of the Grand Junction Mine. There is no reason for supposing that the rocks of the Waihi-Union and Waihi-Silverton Mines are of different character. Samples of the less-altered country from all the Waihi mines show a great similarity, so that they are possibly all of one original type—probably a hypersthene-dacite with some augite and perhaps a little hornblende.
Chemical analyses of the less-altered mine-rocks entirely suport their determination as dacites of a somewhat basic type. The analyses known to the writer show a silica-content ranging from 55 to 61 per cent., with other constituents in proportions normal to an ordinary andesite or dacite that has been somewhat affected by solutions containing carbon-dioxide. The following determinations of silica and water made on rocks from the present lowest level of the Waihi Mine, communicated to the writer by Mr. A. H. V. Morgan, M.A., Director of the Waihi School of Mines, show that the rocks at that level are, if anything, less acidic than in the upper levels :—
| Moisture lost at 100° C. | SiO2. | |
|---|---|---|
| I | 2·30 | 55·13 |
| II | 1·80 | 56·23 |
I, country in crosscut at 1,000 ft. level towards Royal reef, about 50 ft. from No.5 shaft; II, country in crosscut at 1,000 ft. level from No. 5 shaft, about 50 ft. south of No. 4 shaft.
[Footnote] * Sollas, however, regarded some of the rocks he examined as possibly andesites, and his descriptions of specimens 3/2719 and 4/2721 (11, vol. 1, pp. 128–50) may be cited as evidence that he was inclined to call rocks similar to those from the Waihi mines altered dacites or andesites.

(e.) Alteration of Vein-bearing Dacites.
From the preceding pages it will be gathered that near the quartz lodes the dacites are partly silicified, especially-in the groundmass. The original lime-soda feldspars have been almost entirely replaced by valencianite, quartz, probable sericite, and other minerals. Chloritization of the ferromagnesian constituents is prominent. In the sulphide-ore zone more or less pyrite is present.
At some distance from the veins chloritization of the ferro-magnesian minerals is perhaps the most noticeable feature. Many, but not all, of the lime-soda feldspars appear to be replaced by valencianite. Calcite as a secondary mineral is more abundant than in the wall-rocks. Other secondary minerals are quartz, a little pyrite, and perhaps some muscovite and sericite.
By the changes outlined in the last paragraph what may be called the propylitic facies is brought about. The name “propylite” for such rocks, as used by Park and others, is a most convenient term that undoubtedly fills a want, and it is therefore to be regretted that the usage is open to the objection that the name was originally intended to indicate a distinct rock species.
Further discussion of the nature of the orthoclastic feldspar of the altered dacites seems desirable. Some is clearly secondary, and is therefore valencianite. Finlayson has shown that this valencianite is a soda-orthoclase or anorthoclase (14, p. 634). Much more abundant, however, are altered feldspar crystals, now consisting partly of untwinned feldspar of low refractive index, partly of quartz, calcite, and other minerals. Reasons for believing that the feldspar in these crystals is not the remains of the original mineral, but is an alkali (potash-soda) feldspar of secondary character, are the following :—
| (1.) |
In many sections evident transitions from lime-soda feldspars to purely alkali feldspars may be seen. |
| (2.) |
The nearer the lodes, the less the number of recognizable lime-soda feldspars, and the greater the number of alkali feldspars. |
| (3.) |
Chemical analyses show comparatively low percentages of silica and potash in the altered dacites when 30 ft. or more from any large lode. |
| (4.) |
The alkali feldspars usually contain as a decomposition-product calcite, and therefore the presence of lime in the original feldspar is indicated. |
Of the highly altered feldspars, it cannot be asserted that all were originally lime-soda feldspars, but it seems certain that at least the majority were such. There may, however, be reason for thinking that the fresh but rarely seen individuals of apparently pure potash feldspar with binary twinning are primary. It would be difficult to prove the contrary.
If the possibility that some of the alkali feldspar is original be admitted, then it may be supposed either that orthoclase was a constituent of the original andesitic or dacitic magma, or that during or immediately preceding eruption there was some mixing of an andesitic magma with a rhyolitic differentiate. The presence of corroded quartz seems to support the latter hypothesis, which is decidedly an attractive one, however slender a foundation it may rest upon.
(f.) Significance of Propylitic Facies.
It may be asked whether the propylitic facies, as developed at Waihi, does not necessarily involve the formation of secondary alkali feldspar

replacing lime-soda feldspar. It cannot be doubted that such a change has taken place to some extent in the rocks some distance from the veins, but more especially in the wall-rocks. The chief agents in ordinary propylization are without much doubt carbon-dioxide and water, and at Waihi a considerable amount of potash appears to have been introduced when propylization took place, so that apropylitic facies, which is possibly somewhat unusual, * was brought about.
The appearance of the propylitic facies seems closely connected in some way with ultimate silicification in the neighbourhood of planes of fracture—that is to say, with vein-formation. The concentration of metallic minerals, and more especially of gold and silver in the veins, gives a high economic value to any successful attempt to explain the various phenomena attending vein-formation and the localization of ore-shoots and bonanzas. It seems certain that vein-formation in propylitic rocks is due to ascending solutions, which also are presumably the carriers of metallic minerals, and yet in the Hauraki Goldfield the influence of the country on the localization of values is enormous. As the basis of a working hypothesis, it may be suggested that, in effect, a double circulation was set up by some unknown factor or factors; whilst carbon-dioxide and potash in aqueous solution made their way hundreds of feet from the vein-fractures, other substances from the country entered the veins, and probably caused or aided the precipitation of gold, silver, and other metals. Osmosis and electro-chemical agencies may well be supposed to have been concerned in the double circulation thus invoked. It is wished, however, rather to emphasize the conception that there was interaction between the whole body of propylitic rock and the ascending vein-forming solutions during the period of propylization. In other words, propylization and vein-formation were contemporaneous and to a great extent interdependent.
Problems to be solved at Waihi and elsewhere are: What are the conditions necessary to propylization ? Does the propylitic alteration immediately succeed the extrusion and solidification of dacitic or andesitic lavas, or does it take place at a later date ? Is it a long-continued or a rapid process ? Again, does vein-formation accompany propylization as a more or less necessary concomitant, or does it simply follow mainly because rocks with the propylitic facies afford better facilities in some way for vein-formation ? The economic geologist will be further interested to learn, if possible, why quartz veins in propylitic rocks more often contain appreciable quantities of gold and silver than quartz veins in other classes of rocks.
The discovery of the laws regulating the distribution of ore-shoots and bonanzas in the quartz veins of the Hauraki goldfields probably depends in great measure upon the scientific investigation not only of the ore-bodies themselves, but of the enclosing rocks. It has been said by many persons—some with a sound practical knowledge of mining in the Hauraki goldfields—that it is impossible to discover such laws; but the progress made in economic geology during the past twenty years gives hope that rules possessing real value may yet be formulated.
(2.) Stratified Tuff of the Grand Junction Shaft.
At a depth of about 620 ft. the Grand Junction A or No. 1 shaft passes from andesite into fine-grained volcanic débris or tuff, which at 630 ft. to
[Footnote] * A similar facies is developed at Karangahake, and possibly elsewhere in the Hauraki Peninsula.

640 ft. is in well-marked layers with a dip of 21° to 22° to the southward. At some depth not exactly ascertained by the writer this shaft enters the older rocks of the auriferous series.
Pieces of much-altered wood still retaining about 10 per cent. of carbon were common in the material excavated from the shaft at 620 ft. to 630 ft., or thereabouts. These, evidently derived from shrubs or small trees, averaged less than 1 in. in diameter, and were in no case more than a few inches long. Sections made of the enclosing tuff show its fragmentary character very well, especially by reflected light. The constituents appear to be mainly highly decomposed broken feldspar crystals, with a few grains of quartz and other minerals. The secondary products present are calcite, chlorite, pyrite, and nearly opaque kaolinitic matter (probably mainly sericite).
The well-stratified tuff at 630 ft. appears to have suffered but little alteration comparable to that involved in the propylitic facies of the underlying auriferous series. There is therefore some reason for thinking that propylization of the latter rocks preceded the deposition of the tuffs; but before any definite conclusion, if such is possible, can be drawn from the line of reasoning here indicated a more detailed study of the tuff than that made by the writer will be advisable.
(3.) Andesites and Tuffs of the “Second Period.”
(a.) Andesites.
Near Waihi the rocks of the “Second Period” are almost wholly andesitic laves, which in the main closely resemble one another. They are greyish, bluish, or even nearly black rocks, with numerous phenocrysts of feldspar and pyroxene. Macroscopically they differ from the earlier quartzandesites or dacites chiefly in being, as a rule, very much less altered. Under the microscope the younger andesites show practically no orthoclase, and, though primary quartz grains are usually present, these occur to a noticeably less extent than in the older volcanic rocks.
The chief type represented is a hypersthene-augite-andesite with a pilotaxitic or semi-pilotaxitic base. The feldspars are usually fresh and well-twinned basic andesine or acid labradorite. The twinning is generally of the ordinary albite type, but other forms are occasionally seen, and good zonary banding is quite common. In very rare instances a crystal of what appears to be orthoclase may be seen in a section.
Quartz, usually present, is in rounded grains of moderate size, and has the same characters as in the auriferous rocks. The occurrence of a very large bleb of white quartz in a sample of andesite collected near the Mataura track by Mr. F. T. Seelye, of the Waihi School of Mines, deserves note. Sections of this, microscopically examined, were found, except in small areas, to be optically homogeneous.
Augite occurs in the usual way, and is in many cases very finely twinned. A rhombic pyroxene is usually present in abundance. In some slides it predominates over augite, while in others the reverse is the case, but, on the whole, the rhombic and monoclinic pyroxenes are about equal in amount. Generally the rhombic pyroxene is hypersthene, which, while showing well-marked pleochroism, is not of a very ferriferous type, and probably approaches bronzite. In many cases more or less enstatite is present, in some to the total exclusion of hypersthene. The rhombic pyroxenes are decidedly more subject to alteration than the augite. In sections of

specimens from the 500 ft.* levels of the Waihi Extended and Grand Junction Mines they are converted almost wholly into chlorite, and elsewhere are not uncommonly partly chloritized.
In a few slides a little hornblende with resorption border is present. Lozenge-shaped bodies filled with dark dust such as have been observed in the older lavas are not rare, and in the absence of further study may be presumed to represent hornblende that has suffered almost complete resorption.
The other primary minerals present in the hypersthene-augite-andesites are magnetite in small grains, apatite in microscopic needles penetrating phenocrysts of feldspar and pyroxene, and possibly one or two of the rarer rock-forming minerals, such as zircon, in tiny grains.
In the Grand Junction and Waihi Extended Mines alteration of the Second Period rocks overlying the auriferous series is in places very marked. Besides the chloritization of the ferro-magnesian minerals, the feldspars may be much decomposed, with the production of calcite, quartz, and “kaolinitic” matter (probably mainly sericite). Though these effects are seemingly of a propylitic nature, they may be partly due to meteoric solutions. In specimens from shafts and boreholes on the western side of the Martha Hill much alteration is also apparent. In this area serpentine is a prominent secondary mineral in the andesites.
Since the decomposed rocks mentioned in the last paragraph are not known to contain any auriferous-quartz veins, it may be supposed that their alteration was not associated with the formation of ore-bodies. The question deserves investigation, however, for the alteration may possibly have taken place during a period when the lodes in the underlying auriferous series were being enriched, or at a time when values in these lodes were being concentrated in ore-shoots.
In the hills towards the coast-line north-east of Waihi are several varieties of andesitic rocks that differ from the ordinary hypersthene-augite-andesite. These, since they occur somewhat outside the area intended to be described in this paper, will not be further mentioned.
(b.) Tuffs.
On the top of a hill somewhat more than a mile north-west of the Martha Hill is a small outcrop of coarse tuff underlain by a thin clayey layer, below which comes an ordinary andesite. A section made from one of the boulders shows that it is a vesicular hornblende-andesite, with some augite. The vesicles are lined by a yellow undetermined substance. Another boulder proved to be an andesite with beautifully twinned augite and a slightly pleochroic rhombic pyroxene (bronzite). It is quite possible that the tuff under notice belongs to a later period than is here assumed, and ought to be associated with the hornblende-andesites described on page 273.
The andesitic tuffs that appear some miles north-east of Waihi and along the coast-line have not been examined in detail by the writer.
(4.) Rhyolites.
As already mentioned, three types of rhyolite occur near Waihi—one spherulitic, the second (wilsonite) with a peculiar flow structure, and the
[Footnote] * In the Grand Junction Mine the exact depth is 494ft. below the collar of the A or No. 1 shaft.

third a light-coloured fine-grained rock with few phenocrysts. This latter rock contains nests of tridymite, and therefore for the sake of distinction will be designated the “tridymite-rhyolite.”
(a.) Spherulitic Rhyolites.
Macroscopically the spherulitic rhyolites show numerous spherulites, many grains of quartz, and occasional small plates of biotite. A little secondary opal is present in some specimens, and may show good “fire.” Under the microscope quartz appears in large grains, with many gas enclosures. Small crystals of plagioclase and biotite may also be present. The greater part of every section, however, is seen to consist of spherulites. The exact nature of the spherulites in Hauraki rhyolites has been discussed by Rutley (5, pp. 451 et seq.) and Sollas (11, vol. 1, pp. 120–22). Rutley regards them as being composed of devitrified glass, whilst Sollas, beyond adducing evidence opposed to the devitrification theory, makes no very definite pronouncement.* For the present it may be assumed that the spherulites approach orthoclase in composition, and were formed during the final consolidation of the rhyolites.
In a section of rhyolite from the hills about a mile and a half east of Waihi a quartz-grain is seen to form part of a spherulite boundary. Hence in this case the spherulite is obviously of later formation than the quartz. In the same section a phenomenon which may be termed spherulite within spherulite occurs.
At Waihi Beach a beautifully spherulitic rock is traversed by auriferousquartz veins. Sections show that the rock is more or less silicified, much secondary quartz mosaic being present. Feldspar (probably orthoclase) appears in imperfect crystals, one of which is imbedded in a spherulite.
A small vein traversing one of the sections from Waihi Beach consists of a fine quartz mosaic cementing and in part replacing fragments of country. It may from this be inferred that the auriferous veins of this locality, like those at Waihi, are largely replacement veins following fracture planes or zones.
The rhyolites referred to above are more fully described by Sollas (11, vol. 2, pp. 35, 112).
(b.) Wilsonite.
The peculiar rhyolitic rock commonly known as “wilsonite” has been described by Sollas (11, vol. 1, pp. 123, 124; vol. 2, pp. 46, 138). The same rock is mentioned by Park (3, p. 88) and McKay (4, p. 67), and has probably been described by Rutley (5, pp. 460, 461, No. H15).
The freshest obtainable specimens of wilsonite show pinkish or purplish surfaces flecked with numerous black streaks. The fractured rock has a somewhat vitreous lustre. When affected by surface weathering the purplish portion of the rock become nearly white, and the dark portions tend to approach a light-grey colour. Highly weathered rock is of a nearly uniform almost white colour. In places wilsonite tends to pass into a tuff, owing, it is believed, to brecciation of surface portions that solidified before the cessation of flow. Rounded fragments of andesite, usually from ¼ in. to 1 in. in diameter, are very common as inclusions in the wilsonite. These are most noticeable in the highly weathered rock, which also is usually the most tufaceous-looking.
[Footnote] * Sollas stated (11, vol. 1, pp. 122, 124) that he intended to deal more fully with the questions of structure, origin, &c., in a final report. This, apparently, was not written.

Porphyritic grains of quartz and feldspar are easily detected in the unweathered wilsonite. Sections examined under the microscope show that the feldspar is mainly oligoclase and oligoclase-andesine. Some of the more basic feldspars may be andesine, or even acid labradorite. A little orthoclase is probably present. Small fragments of ferro-magnesian minerals also appear.
The greater part of the sections consists of a glassy base nearly, but not quite, isotropic. The bulk of the glassy matter shows a streaky flow structure, but there are also small patches of brownish glass not affected by flow. The dark streaks of the hand-specimen are plainly visible, and from the manner in which they pass into the lighter portions the view that the rock is a lava and not a tuff receives emphatic support.
(c.) Tridymite-rhyolites.
The tridymite-rhyolites in the neighbourhood of Waihi appear as a number of small flows that at several points may be seen breaking through wilsonite. They are greyish-white rocks of even grain, but somewhat harsh texture. Fluxion structure is usually more or less apparent to the eye, and on close examination small glassy feldspars may be detected. Fragments of andesite, and possibly other rocks, are commonly noticeable. In a flow on the east side of the Martha Hill charcoal has been observed at two points—namely, in the Grand Junction A shaft, at a depth of 110ft. to 112ft. from the surface; and in the chamber at No. 3 level adjoining No. 4 shaft, Waihi Mine (depth below shaft-collar, about 195ft.).
Sections of the tridymite-rhyolites from various localities show that they are composed mainly of a glassy base with a fine corrugated flow structure. The scattered phenocrysts are mostly plagioclase (oligoclase or andesine). Rutley has reported sanidine (5, p. 460). Small broken crystals of green hornblende, augite, and hypersthene (Sollas), probably zenoliths, are occasionally observable. An interesting point is that most of the sections show nests of tridymite, which apparently takes the place of free quartz. Slightly decomposed or altered specimens—for example, the charcoal-bearing rock from the Grand Junction shaft—do not show any tridymite, but secondary quartz may be observed. Magnetite and zircon (Sollas) are present in some sections.
The tridymite-rhyolites near Waihi have been minutely described by Rutley (5, pp. 457–60, Nos. H9-H14) and Sollas (11, vol. 2, pp. 14–15 and 66–67).
(5.) Andesitic Rocks of Doubtful Age.
Under this heading are included some of the younger andesitic rocks that were not sufficiently studied to enable the determination of their relative ages with reference to one another and to the rhyolites to be made. The rocks thus occurring are hornblende-andesites of a variable character.
The most notable occurrence of such rocks is the andesite forming the Black Hill, east of Waihi. In places it shows well-marked though not perfect columnar structure. The rock is not very uniform in appearance, but in the main is a dark-grey hornblende-andesite, sections of which, besides abundant hornblende, show a little augite, and in places biotite. The feldspar phenocrysts are probably oligoclase-andesine. A little magnetite and apatite in fine needles are present. A nearly isotropic mineral of very low refractive index was not determined. The base contains numerous feldspar microlites, and with a ¼ in. objective exhibits a kind of feathery appearance under crossed nicols.

Sollas (11, vol. 2, pp. 13, 14) describes a sample of rock from the Black Hill as a light-grey hyalopilitic andesite, with hornblende and biotite. He also mentions the possible presence of quartz and tridymite.
The Black Hill andesite contains in places small fine-grained segregations. One of these on microscopic examination exhibits numerous small feldspar laths of rather basic type (labradorite), together with small phenocrysts of augite, chlorite, and plentiful magnetite imbedded in a glassy base. The structure is reminiscent of an ordinary basalt. The transition border consists of large feldspars near andesine, with some hornblende, enstatite or hypersthene (near bronzite), biotite, and quartz (very rare) imbedded in an obscure apparently more or less glassy base.
One section of a rock from a spot on the east side of the Ohinemuri River about a mile and a half north-east of Waihi shows a hornblende-andesite with some biotite, augite, and hypersthene (rare). A second section contains more hypersthene, but less augite and biotite. It thus approaches very nearly the Black Hill rock described by Sollas.
About two miles and a half west of Waihi, along the course of the water-race to the Victoria Battery (Waikino), there occurs a hornblende-andesite with some augite and enstatite (or bronzite). The two sections made differ considerably in the relative proportions of rhombic pyroxene, so that a want of homogeneity in the rock-mass is again apparent.
Literature.
| (1.) |
1871. Hector, James. “On the Geology of the Cape Colville District.” Rep. N.Z. Geol. Surv. during 1870–71, vol. 6, pp. 88–103. |
| (2.) |
1883. Cox, S. H. “Goldfields of the Cape Colville Peninsula.” Rep. N.Z. Geol. Surv. during 1882, vol. 15, pp. 4–51. |
| (3.) |
1897. Park, James. “The Geology and Veins of the Hauraki Goldfields.” Trans. N.Z. Inst. of Min. Eng., vol. 1. |
| (4.) |
1897. McKay, Alexander. “Report on the Geology of the Cape Colville Peninsula, Auckland.” Mines Report, C.–9, pp. 1–75. |
| (5.) |
1899. Park, James, and Rutley, F. “Notes on the Rhyolites of the Hauraki Goldfields, New Zealand.” Quart. Jour. Geol. Soc., vol. 45, pp. 449–69. |
| (6.) |
1900. Park, James. “Notes on a Hypersthene-andesite from Waihi Mine, Waihi.” Trans. N.Z. Inst., vol. 33, pp. 342–43. |
| (7.) |
1902. Morgan, P. G. “Notes on the Geology, Quartz Reefs, and Minerals of the Waihi Goldfield.” Trans. Aust. Inst. Min. Eng., vol. 8, pp. 164–87. |
| (8.) |
1904. Morgan, P. G. “Water in the Hauraki Goldfield.” Eng. and Min. Journ. of New York, vol. 78, p. 429 (15th September). |
| (9.) |
1905. Lindgren, Waldemar. “The Hauraki Goldfields, New Zealand.” Eng. and Min. Journ. of New York, vol. 79, p. 218 (2nd February). Reprinted in “New Zealand Mines Record,” vol. 8, pp. 370–73 (17th April). |
| (10.) |
1905. Morgan, P. G. “The Hauraki Goldfields, New Zealand.” Eng. and Min. Journ. of New York, vol. 79, p. 861 (4th May). Reprinted in “New Zealand Mines Record,” vol. 8, pp. 465–67 (16th June). |
| (11.) |
1905-6. Sollas, W. J., and McKay, Alexander. “The Rocks of Cape Colville Peninsula, Auckland, New Zealand.” 2 vols. |

| (12.) |
1908. Bell, J. M., and Fraser, C. “The Great Waihi Mine.” Canadian Min. Journ., vol. 29, pp. 388–93 (15th August) and 420–24 (1st September). |
| (13.) |
1908. Maclaren, J. Malcolm. “Gold: its Geological Occurrence and Geographical Distribution.” |
| (14.) |
1909. Finlayson, A. M. “Problems in the Geology of the Hauraki Goldfields, New Zealand.” “Economic Geology,” vol. 4, No. 7, pp. 632–45. |
| (15.) |
1910. Park, James. “The Geology of New Zealand.” |
| (16.) |
1910. Bell, J. M. “The Waihi Goldfield.” Proc. Aust. Inst. Min. Eng., vol. 7, No. 1. |
