
The Titre of New Zealand Mutton Tallows.
[Read before the Philosophical Institute of Canterbury, 1st December, 1926; received by Editor, 24th August, 1927; issued separately, 8th November, 1927.]
This paper summarizes the results of several thousand titre determinations, which have been carried out over a period of seven years in the course of the daily examination of mutton tallows manufactured at a number of factories operating both the North and South Islands of New Zealand.
The titre of a tallow, expressed usually in degrees Centigrade, is the solidifying point of the mixed fatty acids obtained by saponifi-cation and subsequent acidification of fats and oils; the basis of the actual determination of the titre lies in the fact that liquids during solidifying evolve heat (the latent heat of fusion) and a rise in temperature occurs; this rise, not marked in the case of fats and oils, is usually quite distinct with the fatty acids, and the tempera-ture taken is the top point of the rise.
The method of determination used throughout in the results recorded in this paper was that officially recommended by the Associa-tion of Official Agriculaural Chemists, the preliminary saponification being carried out with the glycerol-caustic potash solution.
The results of the investigation are shown in Tables 1 and 2.
In the fat and oil industries, the titre is of great importance, for upon the hardness of a tallow depends its use in various manufac-tured products, which include edible fats such as margarine, lubri-eating greases, soaps, and candles. It is outside the scope of this paper to discuss the various factors which determine the application of tallows of different degrees of hardness to certain specific industrial uses, but sufficient indication has been given as to the technical aspect of the titre in manufacturing processes.
Variations in the titre of a tallow, involve alteration in the pro-portion of stearin and of olein, and this from a chemical standpoint means a marked modification in the constitution of the animal fats, involving the relative amounts of saturated and unsaturated glycerides which are the component parts of the fats produced by the animal in the course of its nutritional functions; thus apart from the com-mercial aspect, the problems connected with the titre of animal fats are of fundamental importance from a physiological standpoint.
In general, the titre or hardness of a tallow is beyond the control of the tallow manufacturer, for it depends upon the breed, age, sex,

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| Mean Latitude °Sth. | 40° | 41 ½° | 43 ½° | 44 ½° | 46° | |||||||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| Range of Lat. °Sth. | 39°–41° | 41°–42° | 42 ½°–44° | 44°–45 ½° | 45 ½°–46 ½° | |||||||||||||
| Titre in Degrees Centigrade. | ||||||||||||||||||
| Max. | Min. | Ave. | Max. | Min. | Ave. | Max. | Min. | Ave. | Max. | Min. | Ave. | Max. | Min. | Ave. | ||||
| December-January | 47.6 | 45.5 | 46.3 | 46.6 | 43.8 | 45.1 | 44.9 | 43.6 | 44.3 | 45.0 | 42.5 | 43.7 | 43.2 | 43.1 | 43.1 | |||
| February | 48.7 | 48.0 | 48.3 | 47.3 | 44.4 | 45.7 | 45.1 | 44.1 | 44.5 | 46.4 | 43.6 | 44.5 | 46.4 | 43.6 | 44.5 | 44.6 | 43.5 | 44.0 |
| March | 49.1 | 47.8 | 48.4 | 46.9 | 45.9 | 46.1 | 45.9 | 44.6 | 45.5 | 46.2 | 44.4 | 45.1 | 45.1 | 44.5 | 44.8 | |||
| April | 48.8 | 47.7 | 48.1 | 47.2 | 45.8 | 46.7 | 46.6 | 45.8 | 46.2 | 47.8 | 45.3 | 45.9 | 45.9 | 44.4 | 45.2 | |||
| May | 48.6 | 46.7 | 47.8 | 47.2 | 46.2 | 46.7 | 46.9 | 45.8 | 46.5 | 47.0 | 45.0 | 45.9 | 45.7 | 44.8 | 45.4 | |||
| June | 48.7 | 48.1 | 48.4 | 46.6 | 46.1 | 46.3 | 47.3 | 45.7 | 46.4 | 47.5 | 44.7 | 45.6 | 45.7 | 44.6 | 45.1 | |||
| July | 48.3 | 48.0 | 48.1 | — | — | — | 47.5 | 45.8 | 47.0 | — | — | — | 45.6 | 44.2 | 45.0 | |||
| Average | 48.2 | 47.2 | 47.2 | 45.4 | 46.0 | 45.1 | 46.7 | 44.7 | 45.6 | 44.5 | ||||||||
| 7 years | 47.9 | 46.1 | 45.8 | 45.1 | 44.7 |
[The section below cannot be correctly rendered as it contains complex formatting. See the image of the page for a more accurate rendering.]
| Mean Latitude °Sth. | 40° | 41 ½° | 43 ½° | 44 ½° | 46° | ||||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| Range of Lat. °Sth. | 39°–41° | 41°–42° | 42 ½°–44° | 44°–45 ½° | 45 ½°–46 ½° | ||||||||||
| Titre in Degrees Centigrade. | |||||||||||||||
| Max. | Min. | Ave. | Max. | Min. | Ave. | Max. | Min. | Ave. | Max. | Min. | Ave. | Max. | Min. | Ave. | |
| December-January | 43.3 | 42.5 | 43.0 | 43.5 | 42.3 | 42.9 | 42.4 | 41.8 | 42.1 | 42.1 | 41.5 | 41.6 | 41.7 | 41.5 | 41.6 |
| February | 45.4 | 43.5 | 44.4 | 43.9 | 42.6 | 43.2 | 42.9 | 42.2 | 42.6 | 42.8 | 41.5 | 42.1 | 43.0 | 41.6 | 42.3 |
| March | 45.0 | 43.6 | 44.5 | 44.0 | 43.4 | 43.7 | 43.4 | 42.8 | 43.2 | 43.1 | 42.3 | 42.7 | 43.3 | 42.3 | 42.7 |
| April | 45.3 | 43.5 | 44.4 | 44.6 | 43.6 | 44.2 | 43.7 | 43.2 | 43.4 | 43.3 | 42.7 | 43.1 | 43.5 | 42.7 | 43.1 |
| May | 45.1 | 43.1 | 44.1 | 44.6 | 44.0 | 44.3 | 44.1 | 42.8 | 43.6 | 43.6 | 42.9 | 43.4 | 43.8 | 42.6 | 43.2 |
| June | 45.4 | 43.4 | 44.4 | 44.6 | 44.2 | 44.4 | 44.1 | 42.4 | 43.6 | 43.8 | 42.7 | 43.4 | 43.4 | 42.6 | 43.2 |
| July | 44.6 | 43.8 | 44.2 | — | — | — | 43.8 | 41.5 | 42.6 | 43.3 | 43.0 | 43.1 | 43.3 | 42.2 | 42.9 |
| Average | 44.6 | 43.3 | 44.0 | 43.3 | 43.3 | 42.5 | 43.0 | 42.3 | 43.4 | 42.4 | |||||
| 7 years | 44.1 | 43.8 | 43.0 | 42.8 | 42.7 |

and the part of the animal from which the fat was removed, and to some extend upon the food of the animal; thus mutton fat is normally harder than beef fat, the fat from a mature animal is harder than that obtained from the younger animal, the fat from the male is generally harder than that from the female, the kidney fats are harder than the intestinal fats, animals fed on pasture generally yield a harder fat than those fed upon oil-cakes.
Throughout New Zealand, sheep and lambs derive their food almost exclusively from pasture and root crops, while oil-bearing feeding-stuffs are seldom if ever used to supplement the diet, hence the fats derived from these animals are largely formed from carbo-hydrates, but the chemical changes involved are still obscure. For all practical purposes the foodstuffs which constitute the diet of sheep and lambs are so similar throughout New Zealand as to introduce no material differences in the carbohydrates which are ultimately converted into fat within the animals.
In the tables, the reference to the mean Latitude South, indicates that of the works handling large quantities of stock for slaughter during a period varying each year from December to July inclusive; the range of Latitude South indicates the approximate latitudes within which most of the stock was received.
The maximum and minimum figures represent respectively the highest and lowest average for the period covered, thus in Table 1, for December-January, mean Latitude 40° S., the maximum of 47.6° for this period was in 1920, whilst the minimum 45.5° was in 1922; for February the maximum 48.7° was in 1925, the minimum 48.0° was in 1921; the seasonal maximum 48.2° was in 1925, the minimum 47.2° was in 1922. The average shows, in each instance, the numerical average for seven years.
No figures are given for the months August-November inclusive, for the reason that relatively a very small quantity of mutton tallow is manufactured during this period.
A study of the figures shows, as might be expected, that there is a gradual increase in the titre as the stock become more mature and older; in general, a certain peak is reached, and then some fall takes place, usually slight but definite; why this should occur at all seems obscure, for since the source of the fat is the carbohydrate content of the feeding stuffs, one does not expect a variation in the stearin-olein ratio to take place, as is indicated by the lower titre; there is the climatic factor, however, for usually the fall is more or less co-incidental with the onset of winter.
The figures also show that there is a definite relationship between the titre and the latitude; this is seen markedly when the seasonal average over seven years is compared with the mean Latitude from which the stock was drawn. For convenience these comparisons are shown in Table 3.

| Mean Latitude S. Degrees. | Caul and Kidney Fats. Degrees. | Intestinal and Visceral Fats. Degrees. |
|---|---|---|
| 40 | 47.9 | 44.1 |
| 41 ½ | 46.1 | 43.8 |
| 43 ½ | 45.8 | 43.0 |
| 44 ½ | 45.1 | 42.8 |
| 46 | 44.7 | 42.7 |
This table brings out clearly the fact that, the lower the Latitude degrees S., the lower is the average titre of fats from a corresponding portion of the animal. In the 40°—41 ½° mean latitudes, the breeds differ to some extent from those in the 43 ½°—46 ½° mean latitudes, but for the most part the differences in breed are not material when the average seasonal output is considered, nor do the carbohydrates from which the fats are built up materially differ.
Probably the differences are due to climatic variations, for in general the different latitudes have certain conditions as to rainfall, temperature, humidity, and sunshine, which vary from those found in other latitudes in the same country; but even when taking these factors into consideration, there are many anomalies and contradictory points which render any one explanation insufficient.
Information received from tallow brokers in Sydney indicates that similar variations as to latitude in Australia affect the titre of Queensland and New South Wales tallows.
For permission to publish this paper and results, acknowledge-ment is made to the New Zealand Refrigerating Company, Ltd., in whose laboratory the work has been carried out.
